<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">De Nicola, F</style></author><author><style face="normal" font="default" size="100%">Alfani, a</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Polycyclic aromatic hydrocarbon contamination in an urban area assessed by Quercus ilex leaves and soil</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental Science and Pollution Research</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">carcinogenic pahs</style></keyword><keyword><style  face="normal" font="default" size="100%">Diagnostic ratios</style></keyword><keyword><style  face="normal" font="default" size="100%">Environmental matrices</style></keyword><keyword><style  face="normal" font="default" size="100%">Light and heavy PAHs</style></keyword><keyword><style  face="normal" font="default" size="100%">Naples urban area</style></keyword><keyword><style  face="normal" font="default" size="100%">PAH toxicity</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year></dates><publisher><style face="normal" font="default" size="100%">Springer Berlin Heidelberg</style></publisher><volume><style face="normal" font="default" size="100%">21</style></volume><pages><style face="normal" font="default" size="100%">7616-7623</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">We investigated the PAH contamination of Naples urban area, densely populated and with high traffic flow, by analyses of environmental matrices: soil and Quercus ilex leaves. Being some PAHs demonstrated to have hazardous effects on human health, the accumulation of carcinogenic and toxic PAHs (expressed as B(a)Peq) was evaluated in the leaves and soil. The main sources of the PAHs were discrim- inated by the diagnostic ratios in the two matrices. The urban area appeared heavily contaminated by PAHs, showing in soil and leaves total PAH concentrations also fivefold higher than those from the remote area. The soil mainly accumulated heavy PAHs, whereas leaves the lightest ones.Median values of carcinogenic PAH concentrations were higher in soil (440 ng g−1 d.w.) and leaves (340 ng g−1 d.w.) fromthe urban than the remote area (60 and 70 ng g−1 d.w., respectively, for soil and leaves). Also, median B(a)Peq concentrations were higher both in soil and leaves from the urban (137 and 63 ng g−1 d.w., respectively) than those from the remote area (19 and 49 ng g−1 d.w., respectively).Different from the soils, the diagnostic ratios found for the leaves discerned PAH sources in the remote and urban areas, highlighting a great contribution of vehicular traffic emission as main PAHsource in the urban area. Responsible</style></abstract></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">De Nicola, F</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author><author><style face="normal" font="default" size="100%">Prati, M V</style></author><author><style face="normal" font="default" size="100%">Alfani, a</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Leaf accumulation of trace elements and polycyclic aromatic hydrocarbons (PAHs) in Quercus ilex L.</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental pollution (Barking, Essex : 1987)</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Air Pollutants</style></keyword><keyword><style  face="normal" font="default" size="100%">Air Pollutants: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Aromatic</style></keyword><keyword><style  face="normal" font="default" size="100%">Aromatic: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Atomic</style></keyword><keyword><style  face="normal" font="default" size="100%">biomonitoring</style></keyword><keyword><style  face="normal" font="default" size="100%">cadmium</style></keyword><keyword><style  face="normal" font="default" size="100%">Cadmium: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">chromium</style></keyword><keyword><style  face="normal" font="default" size="100%">Chromium: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Cities</style></keyword><keyword><style  face="normal" font="default" size="100%">copper</style></keyword><keyword><style  face="normal" font="default" size="100%">Copper: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Environmental Monitoring</style></keyword><keyword><style  face="normal" font="default" size="100%">Environmental Monitoring: methods</style></keyword><keyword><style  face="normal" font="default" size="100%">Iron</style></keyword><keyword><style  face="normal" font="default" size="100%">Iron: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Italy</style></keyword><keyword><style  face="normal" font="default" size="100%">lead</style></keyword><keyword><style  face="normal" font="default" size="100%">Lead: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">PAHs</style></keyword><keyword><style  face="normal" font="default" size="100%">Plant Leaves</style></keyword><keyword><style  face="normal" font="default" size="100%">Plant Leaves: chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Polycyclic Hydrocarbons</style></keyword><keyword><style  face="normal" font="default" size="100%">Quercus</style></keyword><keyword><style  face="normal" font="default" size="100%">Quercus ilex L.</style></keyword><keyword><style  face="normal" font="default" size="100%">Spectrophotometry</style></keyword><keyword><style  face="normal" font="default" size="100%">Trace Elements</style></keyword><keyword><style  face="normal" font="default" size="100%">Trace Elements: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Unwashed and washed leaves</style></keyword><keyword><style  face="normal" font="default" size="100%">Vanadium</style></keyword><keyword><style  face="normal" font="default" size="100%">Vanadium: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Zinc</style></keyword><keyword><style  face="normal" font="default" size="100%">Zinc: analysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2008</style></year></dates><volume><style face="normal" font="default" size="100%">153</style></volume><pages><style face="normal" font="default" size="100%">376-383</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Quercus ilex L. leaves were collected four times in one year at six urban sites and one remote area in order to determine trace element and PAH accumulation through concomitant analyses of unwashed and water-washed leaves. Both unwashed and washed leaves showed the highest amounts of trace elements and PAHs in the urban area. Unwashed leaves showed greater differences between urban and remote areas and among the urban sites than washed leaves for trace element and PAH concentrations. Water-washing resulted in a significant (P&lt;0.001) decrease in leaf concentrations of Cr, Cu, Fe, Pb, V and Zn. By contrast, Cd and total PAH concentrations showed no differences between unwashed and washed leaves.</style></abstract><accession-num><style face="normal" font="default" size="100%">17892907</style></accession-num></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Alfani, a</style></author><author><style face="normal" font="default" size="100%">Nicola, F</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author><author><style face="normal" font="default" size="100%">Prati, M</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Long-term PAH accumulation after bud break in L. leaves in a polluted environment</style></title><secondary-title><style face="normal" font="default" size="100%">Atmospheric Environment</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">air contamination</style></keyword><keyword><style  face="normal" font="default" size="100%">carcinogenic pahs</style></keyword><keyword><style  face="normal" font="default" size="100%">pah dynamics</style></keyword><keyword><style  face="normal" font="default" size="100%">pah leaf accumulation</style></keyword><keyword><style  face="normal" font="default" size="100%">polycyclic aromatic hydrocarbons</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year></dates><volume><style face="normal" font="default" size="100%">39</style></volume><pages><style face="normal" font="default" size="100%">307-314</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The dynamics of polycyclic aromatic hydrocarbon (PAH) concentrations in the leaves of Quercus ilex L. for 16 months after bud break (May 2001–September 2002) were studied at a polluted site in the urban area of Naples by comparison to the dynamics at a control site in the Vesuvius National Park. Twenty-seven PAHs were extracted by sonication and quantiﬁed by GC-MS. Total PAH concentrations in the leaves sampled at the urban site showed a considerable increase from bud break, with the highest values during the winter (about 3-fold greater than the initial value) and a subsequent decrease, unlike the control site. The control site exhibited PAH concentrations one order of magnitude lower than the urban site. At the urban site, the medium molecular weight PAHs, amounting to 72% of the total, appear responsible for the temporal trend, while the low and high molecular weight PAHs (respectively, 10% and 18%) exhibited only narrow variations over time. At the control site, the low, medium and high molecular weight PAHs contributed similarly to the total concentrations (32%, 31% and 37%, respectively); the low molecular weight PAHs showed the widest temporal variations. Carcinogenic PAHs showed a dynamic at the urban site comparable to that shown by the total PAHs. At the control site dibenzo(a,h)anthracene exhibited concentrations higher than at the urban site</style></abstract></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">De Nicola, F</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author><author><style face="normal" font="default" size="100%">Alfani, a</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Assessment of nutritional status and trace element contamination of holm oak woodlands through analyses of leaves and surrounding soils.</style></title><secondary-title><style face="normal" font="default" size="100%">The Science of the total environment</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Available soil elements</style></keyword><keyword><style  face="normal" font="default" size="100%">Micro and macro elements</style></keyword><keyword><style  face="normal" font="default" size="100%">Quercus ilex L.leaves</style></keyword><keyword><style  face="normal" font="default" size="100%">Total soil elements</style></keyword><keyword><style  face="normal" font="default" size="100%">Vesuvius National Park</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2003</style></year></dates><volume><style face="normal" font="default" size="100%">311</style></volume><pages><style face="normal" font="default" size="100%">191-203</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The nutritional status and trace element contamination of holm oak woodlands in Vesuvius National Park were assessed by analyses of Quercus ilex L. leaves and surrounding soils. The concentrations of Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V and Zn were measured in 1-year-old leaves, and in the soils at 0-5 and 15-20 cm depths. The potentially available concentrations were also measured for the soils. The leaf element concentrations were similar to the Q. ilex chemical fingerprint, thus indicating a good nutritional status and the absence of short-term trace element depositions. Total K and V were more abundant in the deep soil layers than in the surface ones, whereas Cd and Pb showed higher values in the surface soils. This suggests that long-term soil accumulations of Cd and Pb are due to atmospheric input. The soil availabilities of Cd, Pb and Zn were high, and Cr availability was very low. A correlation between the available concentrations in the deep soil layers and leaf concentrations was found only for Zn.</style></abstract><accession-num><style face="normal" font="default" size="100%">12826392</style></accession-num></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Alfani, a</style></author><author><style face="normal" font="default" size="100%">Baldantoni, D</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author><author><style face="normal" font="default" size="100%">Bartoli, G</style></author><author><style face="normal" font="default" size="100%">Virzo de Santo, A</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Temporal and spatial variation in C, N, S and trace element contents in the leaves of Quercus ilex within the urban area of Naples.</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental pollution (Barking, Essex : 1987)</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">air pollution biomonitoring</style></keyword><keyword><style  face="normal" font="default" size="100%">leaf elemental analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">no x</style></keyword><keyword><style  face="normal" font="default" size="100%">so 2</style></keyword><keyword><style  face="normal" font="default" size="100%">Trace Elements</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2000</style></year></dates><volume><style face="normal" font="default" size="100%">109</style></volume><pages><style face="normal" font="default" size="100%">119-129</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">This paper presents a comparative analysis of the concentrations of C, N and S and several trace elements (Fe, Mn, Na, Zn, Cu, V, Pb, Ni, Cr, Cd) in leaves of Quercus ilex, an evergreen oak, collected in the urban area of Naples in 1989 and 1996. The samplings were carried out from 25 urban sites (roads with different traffic flows as well as urban and suburban parks) and from two remote areas as controls. Relative to 1989, the values measured in 1996 denote a strong decrement of S, Fe, Na, Pb, and Cr, with the exception of S in control sites. By contrast, C, N and Cd contents were higher in 1996 than in 1989. Cu and Ni showed a conspicuous increment in control sites as well as in urban sites facing the sea and in the parks, while in all the other urban sites these elements decreased remarkably. No significant difference was found in the leaf contents of Mn, Zn and V measured in 1989 relative to 1996. Both in 1989 and 1996 the contents of N, S, Fe, Na, Cu, Pb, V, Ni, Cr and Cd were significantly higher in leaves from urban sites than in the controls, reflecting the high degree of contamination of the urban area. Concentration factors expressed as the ratio of road/control values for most of the elements were still very high in leaves collected in 1996, though remarkably lower than in 1989.</style></abstract><accession-num><style face="normal" font="default" size="100%">15092919</style></accession-num></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Alfani, a</style></author><author><style face="normal" font="default" size="100%">Bartoli, G</style></author><author><style face="normal" font="default" size="100%">Rutigliano, F a</style></author><author><style face="normal" font="default" size="100%">Maisto, G</style></author><author><style face="normal" font="default" size="100%">De Santo, a V</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Trace metal biomonitoring in the soil and the leaves of Quercus ilex in the urban area of Naples.</style></title><secondary-title><style face="normal" font="default" size="100%">Biological trace element research</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Air Pollutants</style></keyword><keyword><style  face="normal" font="default" size="100%">Air Pollutants: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">biomonitoring</style></keyword><keyword><style  face="normal" font="default" size="100%">copper</style></keyword><keyword><style  face="normal" font="default" size="100%">Copper: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Environmental Monitoring</style></keyword><keyword><style  face="normal" font="default" size="100%">Holly Oak</style></keyword><keyword><style  face="normal" font="default" size="100%">Iron</style></keyword><keyword><style  face="normal" font="default" size="100%">Iron: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">lead</style></keyword><keyword><style  face="normal" font="default" size="100%">Lead: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">leaves</style></keyword><keyword><style  face="normal" font="default" size="100%">Manganese</style></keyword><keyword><style  face="normal" font="default" size="100%">Manganese: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Plants</style></keyword><keyword><style  face="normal" font="default" size="100%">Plants: chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">seasonal dynamics</style></keyword><keyword><style  face="normal" font="default" size="100%">Soil</style></keyword><keyword><style  face="normal" font="default" size="100%">Soil: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Trace Elements</style></keyword><keyword><style  face="normal" font="default" size="100%">Trace Elements: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">urban area pollution</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">1996</style></year></dates><volume><style face="normal" font="default" size="100%">51</style></volume><pages><style face="normal" font="default" size="100%">117-131</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The concentrations of Pb, Cu, Fe, and Mn were analyzed in surface deposit and tissue of Quercus ilex leaves from several sites of the urban area of Naples, exposed to different degrees of air pollution. These included some major roads with heavy traffic loads, squares, and three urban parks. The soil from the trunk base area of Q. ilex trees in the same sites was also analyzed for total and available metal contents. Pb, Cu, and Fe contents in the surface deposit and leaf tissue were significantly higher (p &lt; 0.01) in leaves from roadside sites than in leaves from parks; significant correlations were found between deposit- and tissue-contents of Pb, Cu, and Fe. Mn content in leaves from roadside sites and in leaves from parks were similar and Mn content in the leaf deposit was irrelevant. Significant differences (p &lt; 0.001) in both total and available Pb and Cu soil content were found between sampling sites. Also for available Fe and Mn soil content differences among sites were relevant, although the highest values were measured in soil from urban parks. A positive correlation between leaf and soil metal content was found only for Pb, thus suggesting that trace metal contents of leaves directly depend on atmospheric depositions. Seasonal variations of Pb, Cu, and Fe were pronounced at a polluted site, whereas no relevant seasonal variation was observed at a control site; moreover, metal accumulation was high at the polluted site. Mn content and seasonal dynamics were comparable at control and polluted sites.</style></abstract><accession-num><style face="normal" font="default" size="100%">8834387</style></accession-num></record></records></xml>