<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sánchez del Pulgar, J</style></author><author><style face="normal" font="default" size="100%">Soukoulis, C</style></author><author><style face="normal" font="default" size="100%">Carrapiso, A I</style></author><author><style face="normal" font="default" size="100%">Cappellin, L</style></author><author><style face="normal" font="default" size="100%">Granitto, P</style></author><author><style face="normal" font="default" size="100%">Aprea, E</style></author><author><style face="normal" font="default" size="100%">Romano, A</style></author><author><style face="normal" font="default" size="100%">Gasperi, F</style></author><author><style face="normal" font="default" size="100%">Biasioli, F</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Effect of the pig rearing system on the final volatile profile of Iberian dry-cured ham as detected by PTR-ToF-MS</style></title><secondary-title><style face="normal" font="default" size="100%">Meat Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">aldehydes</style></keyword><keyword><style  face="normal" font="default" size="100%">Aldehydes: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Animal Feed</style></keyword><keyword><style  face="normal" font="default" size="100%">Animal Husbandry</style></keyword><keyword><style  face="normal" font="default" size="100%">Animal Husbandry: methods</style></keyword><keyword><style  face="normal" font="default" size="100%">Animals</style></keyword><keyword><style  face="normal" font="default" size="100%">diet</style></keyword><keyword><style  face="normal" font="default" size="100%">Dietary Fats</style></keyword><keyword><style  face="normal" font="default" size="100%">Dietary Fats: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Dietary Fats: pharmacology</style></keyword><keyword><style  face="normal" font="default" size="100%">Dry cured ham</style></keyword><keyword><style  face="normal" font="default" size="100%">Ions</style></keyword><keyword><style  face="normal" font="default" size="100%">Ketones</style></keyword><keyword><style  face="normal" font="default" size="100%">Ketones: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Mass spectrometry</style></keyword><keyword><style  face="normal" font="default" size="100%">Mass Spectrometry: methods</style></keyword><keyword><style  face="normal" font="default" size="100%">meat</style></keyword><keyword><style  face="normal" font="default" size="100%">Meat: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Nuts</style></keyword><keyword><style  face="normal" font="default" size="100%">Oleic Acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Oleic Acid: pharmacology</style></keyword><keyword><style  face="normal" font="default" size="100%">Poaceae</style></keyword><keyword><style  face="normal" font="default" size="100%">Proton transfer reaction mass spectrometry</style></keyword><keyword><style  face="normal" font="default" size="100%">Quercus</style></keyword><keyword><style  face="normal" font="default" size="100%">Rearing system</style></keyword><keyword><style  face="normal" font="default" size="100%">subcutaneous fat</style></keyword><keyword><style  face="normal" font="default" size="100%">Subcutaneous Fat: metabolism</style></keyword><keyword><style  face="normal" font="default" size="100%">Sulfur Compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">Sulfur Compounds: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Swine</style></keyword><keyword><style  face="normal" font="default" size="100%">Switchable reagent ions</style></keyword><keyword><style  face="normal" font="default" size="100%">Time of flight</style></keyword><keyword><style  face="normal" font="default" size="100%">Volatile Organic Compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">Volatile Organic Compounds: analysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year></dates><publisher><style face="normal" font="default" size="100%">Elsevier Ltd</style></publisher><volume><style face="normal" font="default" size="100%">93</style></volume><pages><style face="normal" font="default" size="100%">420-428</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The volatile compound proﬁle of dry-cured Iberian ham lean and subcutaneous fat from pigs fattened outdoors on acorn and pasture (Montanera) or on high-oleic concentrated feed (Campo) was investigated by proton transfer reaction time-of-ﬂight mass spectrometry. In addition to the usual proton transfer ionization the novel switchable reagent ions system was implemented which allows the use of different precursor ions (H3O+ , NO+ and O2 + ). The analysis of the lean and subcutaneous fat volatile compounds allowed a good sample discrimination according to the diet. Differences were evident for several classes of compounds: in particular, Montanera hams showed higher concentrations of aldehydes and ketones and lower concentrations of sulfur-containing compounds compared to Campo hams. The use of NO+ as precursor ion conﬁrmed the results obtained with H3O+ in terms of classiﬁcation capability and provides additional analytical insights.</style></abstract><accession-num><style face="normal" font="default" size="100%">23273445</style></accession-num></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Del Pulgar, José Sánchez</style></author><author><style face="normal" font="default" size="100%">Soukoulis, Christos</style></author><author><style face="normal" font="default" size="100%">Biasioli, Franco</style></author><author><style face="normal" font="default" size="100%">Cappellin, Luca</style></author><author><style face="normal" font="default" size="100%">García, Carmen</style></author><author><style face="normal" font="default" size="100%">Gasperi, Flavia</style></author><author><style face="normal" font="default" size="100%">Granitto, Pablo</style></author><author><style face="normal" font="default" size="100%">Märk, Tilmann D.</style></author><author><style face="normal" font="default" size="100%">Piasentier, Edi</style></author><author><style face="normal" font="default" size="100%">Schuhfried, Erna</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Rapid characterization of dry cured ham produced following different PDOs by proton transfer reaction time of flight mass spectrometry (PTR-ToF-MS).</style></title><secondary-title><style face="normal" font="default" size="100%">Talanta</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Animals</style></keyword><keyword><style  face="normal" font="default" size="100%">Data Mining</style></keyword><keyword><style  face="normal" font="default" size="100%">Dry cured ham</style></keyword><keyword><style  face="normal" font="default" size="100%">Flavour compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">Food Handling</style></keyword><keyword><style  face="normal" font="default" size="100%">Food Handling: methods</style></keyword><keyword><style  face="normal" font="default" size="100%">Italy</style></keyword><keyword><style  face="normal" font="default" size="100%">Mass spectrometry</style></keyword><keyword><style  face="normal" font="default" size="100%">Mass Spectrometry: methods</style></keyword><keyword><style  face="normal" font="default" size="100%">Meat Products</style></keyword><keyword><style  face="normal" font="default" size="100%">Meat Products: analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">PDO</style></keyword><keyword><style  face="normal" font="default" size="100%">PTR-MS</style></keyword><keyword><style  face="normal" font="default" size="100%">PTR-ToF-MS</style></keyword><keyword><style  face="normal" font="default" size="100%">Spain</style></keyword><keyword><style  face="normal" font="default" size="100%">Swine</style></keyword><keyword><style  face="normal" font="default" size="100%">volatile compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">Volatile Organic Compounds</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2011///</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://www.ncbi.nlm.nih.gov/pubmed/21645714</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">85</style></volume><pages><style face="normal" font="default" size="100%">386 - 393</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">In the present study, the recently developed proton transfer reaction time of flight mass spectrometry (PTR-ToF-MS) technique was used for the rapid characterization of dry cured hams produced according to 4 of the most important Protected Designations of Origin (PDOs): an Iberian one (Dehesa de Extremadura) and three Italian ones (Prosciutto di San Daniele, Prosciutto di Parma and Prosciutto Toscano). In total, the headspace composition and respective concentration for nine Spanish and 37 Italian dry cured ham samples were analyzed by direct injection without any pre-treatment or pre-concentration. Firstly, we show that the rapid PTR-ToF-MS fingerprinting in conjunction with chemometrics (Principal Components Analysis) indicates a good separation of the dry cured ham samples according to their production process and that it is possible to set up, using data mining methods, classification models with a high success rate in cross validation. Secondly, we exploited the higher mass resolution of the new PTR-ToF-MS, as compared with standard quadrupole based versions, for the identification of the exact sum formula of the mass spectrometric peaks providing analytical information on the observed differences. The work indicates that PTR-ToF-MS can be used as a rapid method for the identification of differences among dry cured hams produced following the indications of different PDOs and that it provides information on some of the major volatile compounds and their link with the implemented manufacturing practices such as rearing system, salting and curing process, manufacturing practices that seem to strongly affect the final volatile organic profile and thus the perceived quality of dry cured ham.</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><notes><style face="normal" font="default" size="100%">The following values have no corresponding Zotero field:&lt;br/&gt;accession-num: 21645714</style></notes></record></records></xml>